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91.
Detoxification of Chemical Warfare Agents Using a Zr6‐Based Metal–Organic Framework/Polymer Mixture 下载免费PDF全文
Dr. Su‐Young Moon Emmanuel Proussaloglou Gregory W. Peterson Dr. Jared B. DeCoste Morgan G. Hall Dr. Ashlee J. Howarth Prof. Joseph T. Hupp Prof. Omar K. Farha 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(42):14864-14868
Owing to their high surface area, periodic distribution of metal sites, and water stability, zirconium‐based metal–organic frameworks (Zr6‐MOFs) have shown promising activity for the hydrolysis of nerve agents GD and VX, as well as the simulant, dimethyl 4‐nitrophenylphosphate (DMNP), in buffered solutions. A hurdle to using MOFs for this application is the current need for a buffer solution. Here the destruction of the simulant DMNP, as well as the chemical warfare agents (GD and VX) through hydrolysis using a MOF catalyst mixed with a non‐volatile, water‐insoluble, heterogeneous buffer is reported. The hydrolysis of the simulant and nerve agents in the presence of the heterogeneous buffer was fast and effective. 相似文献
92.
W.-S. Jung F. Z. Wang S. Havlin T. Kaizoji H.-T. Moon H. E. Stanley 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,62(1):113-119
We investigate scaling and memory effects in return intervals between price volatilities above a certain threshold q for the
Japanese stock market using daily and intraday data sets. We find that the distribution of return intervals can be approximated
by a scaling function that depends only on the ratio between the return interval τ and its mean 〈τ〉. We also find memory effects
such that a large (or small) return interval follows a large (or small) interval by investigating the conditional distribution
and mean return interval. The results are similar to previous studies of other markets and indicate that similar statistical
features appear in different financial markets. We also compare our results between the period before and after the big crash
at the end of 1989. We find that scaling and memory effects of the return intervals show similar features although the statistical
properties of the returns are different. 相似文献
93.
Choi EY Kim D Hong BK Kwon HM Song YG Byun KH Park HY Whang KC Kim HS 《Experimental & molecular medicine》2002,34(6):391-400
Chlamydia pneumoniae infection implicated as an important etiologic factor of atherosclerosis, especially in coronary artery disease (CAD), was found in vitro to be associated with the induction of matrix metalloproteinases (MMPs). An extracellular matrix metalloproteinase inducer (EMMPRIN)/ membrane-type 1 matrix metalloproteinase (MT1-MMP) system which induces and activates MMPs, is suggested to be functional and were upregulated in the failing myocardium. However, the upstream regulation of MMPs by C. pneumoniae within atheroma itself remains unclear. We evaluated the seroepidemiologic study of C. pneumoniae infection in CAD patients (n= 391) and controls (n=97) and performed histopathological and in vitro analysis in atherosclerotic vascular tissues obtained from patients with seropositive to C. pneumoniae (n=20), by using immunochemistry for C. pneumoniae, EMMPRIN/MT1-MMP, MMP-2, and MMP-9. The seropositive rates of both anti-C. pneumoniae IgG and IgA were 56.7% in CAD group and 43.3% in control group (P=0.033). Seropositive rate was increased in subgroups of CAD patients without conventional coronary risk factors compared to those with conventional risk factors. Immunoreactivities of EMMPRIN, MT1-MMP, MMP-2, and MMP-9 were increased in the atheromatous plaque itself, predominantly in immunoreactive macrophages/mononuclear cells to C. pneumoniae. Furthermore, Western blot analysis showed that EMMPRIN and MMP-2 were detected more prominently in atherosclerotic tissues infected with C. pneumoniae compared to control tissues. Zymographic analysis revealed that activities of MMP-2 and MMP-9 were more increased in atherosclerotic tissues infected with C. pneumoniae compared to control tissues. The present study demonstrated upstream regulation of MMPs can be induced by C. pneumoniae within atheromatous plaque itself. These findings help to understand the potential role of C. pneumoniae in the progression of atherosclerosis. 相似文献
94.
95.
[reaction: see text] Intramolecular Prins-type reactions of compounds having both functionalities of homoallyl alcohol and acetal moiety are described. The intramolecular Prins cyclizations were performed using indium trichloride in chloroform or 25% aqueous THF. Both 9-oxabicyclo[3.3.1]nonane and 3,9-dioxabicyclo[3.3.1]nonane compounds were successfully obtained in moderate yields. 相似文献
96.
[reaction: see text] 2'-Deoxy-2'-C-difluoromethylene-4'-thiocytidine (4) as a potential antitumor agent was synthesized starting from L-xylose via 2-deoxy-2-C-difluoromethylene-4-thiosugar as a key intermediate. An elimination product, 8, was always formed as the major product during removal of the protecting groups under acidic or basic conditions. However, utilizing neutral reaction conditions to remove the protecting groups afforded the desired product 4 exclusively. 相似文献
97.
Photonic crystal fiber coupler 总被引:3,自引:0,他引:3
Fiber couplers made with photonic crystal fibers (PCF) are reported. Two types of PCF were fabricated by means of stacking a group of silica tubes around a silica rod and drawing them. The fiber couplers were made by use of the fused biconical tapered method. With a fiber that had five hexagonally stacked layers of air holes, a 33/67 coupling ratio was obtained, and with a one-layer four-hole fiber, a 48/52 coupling ratio was obtained. The fabrication processes and the characteristics of the PCFs and the PCF couplers are presented. 相似文献
98.
H. Suzuki T. Ohtsuka S. Kawarazaki N. Kunitomi R.M. Moon R.M. Nicklow 《Solid State Communications》1984,49(12):1157-1160
A neutron diffraction experiment on the hyperfine enhanced nuclear spin system of HoVO4 has been carried out following adiabatic demagnetization cooling. Below 4.5 mK we observed magnetic diffraction peaks due to antiferromagnetic order of the hyperfine enhanced nuclear spin system. A spin-flop transition in an applied magnetic field of about 80 Oe was also observed. The neutron diffraction results are consistent with the magnetic structural model proposed by Bleaney on the basis of dipolar energy considerations. 相似文献
99.
J.W Moon 《Journal of Combinatorial Theory, Series A》1980,28(1):98-102
If α = {α0, α1,…, αn} and β = {β0, β1,…, βn} are two non-decreasing sets of integers such that α0 = 0 < β0, αn < βn = n, and αi < i < βi for 1 ? i ? n ? 1, let L denote the set of lattice points (p, q) such that 0 ? p ? n and αp ? q ? βp. We determine all such regions L with the property that the number of lattice paths from (0, 0) to (p, p) in L is the Catalan number for 0 ? p ? n. 相似文献
100.
J.W. Moon 《Linear and Multilinear Algebra》1976,4(3):177-178
Mirsky and Erdos and Mine have given criteria for the existence of a non-negative square matrix with prescribed diagonal entries and row and column sums; it is shown that this result follows from the supply-demand theorem for flows in networks. 相似文献